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Figure 5E shows the Zn 2p XPS region of fully discharged (0.2 V) and fully charged (1.3 V) electrodes in the second cycle. The intensity of Zn 2p 3/2 (1021.9 eV) and Zn 2p 1/2 (1045.2 eV) at the charged state is far below that at the discharged state, which further confirms the insertion/extraction of Zn 2+ into/from the MoS 2 crystals.

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As a result, Zn//Zn symmetric cells with the TFA electrolyte remain stable for over 1360 h and 800 h at high current densities of 5 mA cm −2 and 40 mA cm −2, respectively. The TFA electrolyte also enables Zn//5,7,12,14-pentacenetetrone full cells and Zn//active carbon capacitors to perform steadily for 10 000 cycles at 25 °C and 70 °C, …

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